PUBLICATIONS

250. Tsutsumi, Y., Sakamoto, N., Hirose, K., Tagawam S,m Umemoto, K, Ohishi, Y., Yurimoto, H., Retention of water in subducted slabs under core–mantle boundary conditions. Nature Geoscience 17, 697–704, https://doi.org/10.1038/s41561-024-01464-8, 2024.

249. Okuda, Y., Hirose, K., Ohta, K., Kawaguchi-Imada, S., Oka, K., Electrical conductivity of dense MgSiO3 melt under static compression. Geophysical Research Letters, 51, e2024GL109741. https://doi.org/10.1029/2024GL109741, 2024.

248. Yokoo, S., Hirose, K., Melting experiments on Fe-S-O-C alloys at Martian core conditions: Possible structures in the O- and C-bearing core of Mars, Geochimica et Cosmochimica Acta, 378, 234-244, https://doi.org/10.1016/j.gca.2024.06.027, 2024.

247. Takezawa, H., Hsu, H., Hirose, K., Sakai, F., Fu, S., Gomi, H., Formation of Iron-Helium Compounds under High Pressure, PREPRINT, arXiv, https://doi.org/10.48550/arXiv.2405.11810, 2024

246. Mita, S., Tagawa, S., Hirose, K., Ikuta, N., Fe-FeH Eutectic Melting Curve and the Estimates of Earth’s Core Temperature and Composition, PREPRINT, arXiv, https://doi.org/10.48550/arXiv.2405.09890, 2024

245. Oka, K., Inada, M., Okuda, Y., Hirose, K., Leveraging oxide reactive sputtering for thermal insulation in laser-heated diamond anvil cell, High Pressure Research, 44(2), 159–167. https://doi.org/10.1080/08957959.2024.2346171, 2024.

244. Nagaya, Y., Yagi, T., Ebina, R., Hirose, K., Kodama, M., Hirai, S., Ohta, K., Picosecond acoustics on iron and nickel in an internal-resistive- heated diamond anvil cell to 50 GPa and 2000 K, PREPRINT (Version 1) available at Research Square [https://doi.org/10.21203/rs.3.rs-4332446/v1], 2024.

243. Yokoo, S., Umemoto, K., Hirose, K., Equation of State of Liquid Fe7C3 and Thermodynamic Modeling of the Liquidus Phase Relations in the Fe-C System, Journal of Geophysical Research: Solid Earth, 129, 3, e2023JB028116. https://doi.org/10.1029/2023JB028116, 2024.

242. Ikuta, N., Sakamoto, N., Tagawa, S., Hirose, K., Tsutsumi, Y., Yokoo, S., Yurimoto H., Pressure dependence of metal–silicate partitioning explains the mantle phosphorus abundance, Scientific Reports,14, 1194 (2024). https://doi.org/10.1038/s41598-024-51662-y, 2024.

241. Gomi, H., Hirose, K., Impurity Resistivity of the Earth’s Inner Core,Journal of Geophysical Research: Solid Earth, 128, 11, e2023JB027097. https://doi.org/10.1029/2023JB027097, 2023.

240. Sakai, F., Hirose, K., Morard, G., Partitioning of silicon and sulfur between solid and liquid iron under core pressures: Constraints on Earth’s core composition, Earth and Planetary Science Letters, 624, 118449, https://doi.org/10.1016/j.epsl.2023.118449, 2023.

239. Ohta, K., Suehiro, S., Kawaguchi, S.I., Okuda, Y., Wakamatsu, T., Hirose, K., Ohishi, Y., Kosama, M., Hirai, S., Azuma, S., Measuring the Electrical Resistivity of Liquid Iron to 1.4 Mbar, Measuring the Electrical Resistivity of Liquid Iron to 1.4 Mbar, 130, 26, 266301, https://doi.org/10.1103/PhysRevLett.130.266301, 2023.

238. Park, Y., Yonemitsu, K., Hirose, K., Kuwayama, Y., Azuma, S., Ohta, K., Viscosity of Earth’s inner core constrained by Fe–Ni interdiffusion in Fe–Si alloy in an internal-resistive-heated diamond anvil cell, American Mineralogist, 108, 6, 1064-1071. https://doi.org/10.2138/am-2022-8541, 2023.

237. Nagaya, Y., Gomi, H., Ohta, K., Hirose, K. Equations of state for B2 and bcc Fe1-xSix, Physics of the Earth and Planetary Interiors, 341, 107046, https://doi.org/10.1016/j.pepi.2023.107046, 2023.

236. Okuda, Y., Oka, K., Hikosaka, K., Hirose, K.,, Novel non-Joule heating technique: Externally laser-heated diamond anvil cell. Review of Scientific Instruments, 94, 043901, https://doi.org/10.1063/5.0122111, 2023.

235. Hasegawa, A., Ohta, K., Yagi, T., Hirose, K, Thermal conductivity of platinum and periclase under extreme conditions of pressure and temperature. High Pressure Research, 43:1, 68-80, https://doi.org/10.1080/08957959.2023.2193892, 2023.

234. Tagawa, S., Helffrich, G., Hirose, K., Ohishi, Y., High-Pressure Melting Curve of FeH: Implications for Eutectic Melting Between Fe and Non-Magnetic FeH. Journal of Geophysical Research: Solid Earth, 127, e2022JB024365. https://doi.org/10.1029/2022JB024365, 2022.

233. Gomi, H., Hirose, K., Magnetism and equation of states of fcc FeHx at high pressure. American Mineralogist, 108, 2043-2050, https://doi.org/10.2138/am-2022-8452, 2023.

232. Oka, K., Ikuta, N., Tagawa, S., Hirose, K., Ohishi, Y., Melting Experiments on Fe-O-H and Fe-H: Evidence for Eutectic Melting in Fe-FeH and Implications for Hydrogen in the Core. Geophysical Research Letters, e2022GL099420. https://doi.org/10.1029/2022GL099420, 2022.

231. Hikosaka, K., Tagawa, S., Hirose, K., Okuda, Y., Oka, K., Umemoto, K., Ohishi, Y., Melting phase relations in Fe–Si–H at high pressure and implications for Earth’s inner core crystallization. Scientific Reports, 12, 10000, https://doi.org/10.1038/s41598-022-14106-z, 2022.

230. Sakai, F., Hirose, K., Umemoto, K., Melting experiments on Fe-C-O to 200 GPa; liquidus phase constraints on core composition. Geochemical Perspectives Letters, 22, 1-4, https://doi.org/10.7185/geochemlet.2218, 2022.

229. Yokoo, S., Edmund, E., Morard, G., Baron, M.A., Boccato, S., Decremps, F., Hirose, K., Pakhomova, A., Antonangeli, D., Composition-dependent thermal equation of state of B2 Fe-Si alloys at high pressure. American Mineralogist, in press.

228. Ozawa, K., Hirose, K., Takahashi, Y., High-Pressure XAFS Measurements of the Coordination Environments of Fe2+ and Fe3+ in Basaltic Glasses. Journal of Geophysical Research: Solid Earth, 127, e2021JB023902, https://doi.org/10.1029/2021JB023902, 2022.

227. Oka, K., Tateno, S., Kuwayama, Y., Hirose, K., Nakajima, Y., Umemoto, K., Tsujino, N., I-Kawaguchi, S., A cotunnite-type new high-pressure phase of Fe2S. American Mineralogist, in press.

226. Tagawa, S., Gomi, H., Hirose, K., Ohishi, Y., High-Temperature Equation of State of FeH: Implications for Hydrogen in Earth’s Inner Core. Geophysical Research Letters, 49, e2021GL096260. https://doi.org/10.1029/GL096260, 2022.

225. Yokoo, S., Hirose, K., Tagawa, S., Morard, G., Ohishi, Y., Stratification in planetary cores by liquid immiscibility in Fe-S-H. Nature Communications, 13, 644, https://doi.org/10.1038/s41467-022-28274-z, 2022.

224. Kuwayama, Y., Hirose, K., Codden, L., Kusakabe, M., Tateno, S., Ohishi, Y., Post-Perovskite Phase Transition in the Pyrolitic Lowermost Mantle: Implications for Ubiquitous Occurrence of PostPerovskite Above CMB. Geophysical Research Letters, 49, e2021GL096219, https://doi.org/10.1029/2021GL096219, 2022.

223. Edmund, E., Morard, G., Baron, M.A., Rivoldini, A., Yokoo, S., Boccato, S., Hirose, K., Pakhomova, A., Antonangeli, D., The Fe-FeSi phase diagram at Mercury’s core conditions. Nature Communications, 13, 387, https://doi.org/10.1038/s41467-022-27991-9, 2022.

222. Zhang, Z., Zhang DB., Onga, K., Hasegawa, A., Ohta, K., Hirose, K., Wentzcovitch, RM., Thermal conductivity of CaSiO3 perovskite at lower mantle conditions. Physical Review B, 104 (18), 184101, https://doi.org/10.1103/PhysRevB.104.184101, 2021.

221. Hirose, K., Wood, B., Vočadlo, L., Light elements in the Earth’s core. Nature Reviews Earth & Environment, 2 (9), 645-658, https://doi.org/10.1038/s43017-021-00203-6, 2021.

220. Hasegawa, M., Hirose, K., Oka, K., Ohishi, Y., Liquidus Phase Relations and Solid‐Liquid Partitioning in the Fe‐Si‐C System Under Core Pressures. Geophysical Research Letters, 48 (13), e2021GL092681, https://doi.org/10.1029/2021GL092681, 2021.

219. Ozawa, K., Hirose, K., Kuwayama, Y., Takahashi, Y., The pressure-induced local structural change around tungsten in silicate glass. Geochemical Perspectives Letters, 18, 6-10, https://doi.org/10.7185/geochemlet.2116, 2021.

218. Tagawa, S., Sakamoto, N., Hirose, K., Hernlund, J., Ohishi, Y., Yurimoto, H., Experimental evidence for hydrogen incorporation into Earth’s core. Nature Communications, 12, 2588, https://doi.org/10.1038/s41467-021-22035-0, 2021.

217. Ohta, K., Hirose, K., The thermal conductivity of the Earth’s core and implications for its thermal and compositional evolution. National Science Review, 8 (4), nwaa303, https://doi.org/10.1093/nsr/nwaa303, 2021.

216. Okuda, Y., Kimura, S., Ohta, K., Park, Y., Wakamatsu, T., Mashino, I., Hirose, K., A cylindrical SiC heater for an externally heated diamond anvil cell to 1500 K. Review of Scientific Instruments, 92, 015119, https://doi.org/10.1063/5.0036551, 2021.

215. Helffrich, G., Hirose, K., Nomura, R., Thermodynamical modeling of liquid Fe‐Si‐Mg‐O: Molten magnesium silicate release from the core. Geophysical Research Letters, 47 (21), e2020GL089218, https://doi.org/10.1029/2020GL089218, 2020.

214. Kinoshita, D., Nakajima, Y., Kuwayama, Y., Hirose, K., Iwamoto, A., Ishikawa, D., Baron, A.Q.R, Sound Velocity of Liquid Fe–P at High Pressure. physica status solidi (b), 257 (11), 2000171, https://doi.org/10.1002/pssb.202000171, 2020.

213. Nakajima, Y., Araki, S., Kinoshita, D., Hirose, K., Tateno, S., I-Kawaguchi, S., Hirao, N., New pressure-induced phase transition to Co2Si-type Fe2P. American Mineralogist, 105 (11), 1752-1755, https://doi.org/10.2138/am-2020-7574, 2020.

212. Okuda, Y., Ohta, K., Hasegawa, A., Yagi, T., Hirose, K.,, I-Kawaguchi, S., Ohishi, Y., Thermal conductivity of Fe-bearing post-perovskite in the Earth’s lowermost mantle. Earth and Planetary Science Letters, 547, https://doi.org/10.1016/j.epsl.2020.116466, 2020.

211. Okuda, Y., Ohta, K., Sinmyo, R., Hirose, K., Ohishi, Y., Anomalous compressibility in (Fe, Al)-bearing bridgmanite: implications for the spin state of iron. Physics and Chemistry of Minerals, 47, 40, https://doi.org/10.1007/s00269-020-01109-3, 2020.

210. Inoue, H., Suehiro, S., Ohta, L., Hirose, K., Ohishi, Y., Resistivity saturation of hcp Fe-Si alloys in an internally heated diamond anvil cell: A key to assessing the Earth’s core conductivity. Earth and Planetary Science Letters, 543, https://doi.org/10.1016/j.epsl.2020.116357, 2020.

209. Nakajima, Y., I-Kawaguchi, S., Hirose, K., Tateno, S., Kuwayama, Y., Sinmyo, R., Ozawa, H., Tsutsui, A., Uchiyama, H., Baron, A.Q.R, Silicon-depleted present-day Earth’s outer core revealed by sound velocity measurements of liquid Fe-Si alloy. Journal of Geophysical Research, Solid Earth 125, https://doi.org/10.1029/2020JB019399, 2020.

208. Kato, C., Umemoto, K., Ohta, K., Tagawa, S., Hirose, K., Ohishi, Y., Stability of fcc phase FeH to 137 GPa. American Mineralogist 105 (6), 917-921, https://doi.org/10.2138/am-2020-7153, 2020.

207. Nishida, K., Shibazaki, Y., Terasaki, H., Higo, Y., Suzuki, A., Funamori, N., Hirose, K., Effect of sulfur on sound velocity of liquid iron under Martian core conditions. Nature Communications 11, 1954, https://doi.org/10.1038/s41467-020-15755-2, 2020.

206. Kuwayama, Y., Morard, G., Nakajima, Y., Hirose, K., Baron, A.Q.R, Kawaguchi, S.I., Tsuchiya, T., Ishikawa, D., Hirao, N., Ohishi, Y., Equation of state of liquid iron under extreme conditions, Physical Review Letters 124, 165701, https://doi.org/10.1103/PhysRevLett.124.165701, 2020.

205. Umemoto, K., Hirose, K., Chemical compositions of the outer core examined by first principles calculations, Earth and Planetary Science Letters, 531, https://doi.org/10.1016/j.epsl.2019.116009, 2020.

204. Tateno, S., Ozawa, H., Hirose, K., Suzuki, T., I-Kawaguchi, S., Hirao, N., Fe2S: The Most Fe-Rich Iron Sulfide at the Earth’s Inner Core Pressures, Geophysical Research Letters, 46, https://doi.org/10.1029/2019GL085248, 2019.

203. Oka, K., Hirose, K., Tagawa, S., Kidokoro, Y., Nakajima, Y., Morard, G., Coudurier, N., and Fiquet, G., Melting in the Fe-FeO system to 204 GPa: Implications for oxygen in Earth’s core, American Mineralogist, 104 (11), 1603-1607,doi.org:10.2138/am-2019-7081, 2019.

202. Suehiro, S., Wakamatsu, T., Ohta, K., Hirose, K., Ohishi, Y., High-temperature electrical resistivity measurements of hcp iron to Mbar pressure in an internally resistive heated diamond anvil cell. High Pressure Research, 39 (4), 579-587, https://doi.org/10.1080/08957959.2019.1692008, 2019.

201. Hikosaka, K., Sinmyo, R., Hirose, K., Ishii, T., Ohishi, Y. The stability of Fe5O6 and Fe4O5 at high pressure and temperature, American Mineralogist, 104 (9), 1359-1359, https://doi.org/10.2138/am-2019-7097, 2019.

200. Okuda, Y., Ohta, K., Sinmyo, R., Hirose, K., Yagi, T., Ohishi, Y., Effect of spin transition of iron on the thermal conductivity of (Fe, Al)-bearing bridgmanite, Earth and Planetary Science Letters, 520 (15), 188-198, https://doi.org/10.1016/j.epsl.2019.05.042, 2019.

199. Hirose, K., Tagawa, S., Sinmyo, R., Morard, G., Ohishi, Y. Genda, H. Hydrogen limits carbon in liquid iron, Geophysical Research Letters, 46, https://doi.org/10.1029/2019GL082591, 2019.

198. Yokoo, S., Hirose, K., Sinmyo, R., Tagawa, S., Melting experiments on liquidus phase relations in the Fe-S-O ternary system under core pressures, Geophysical Research Letters, 46, https://doi.org/10.1029/2019GL082277, 2019.

197. Caracas, R., Hirose, K., Nomura, R., Ballmer, M.D., Melt–crystal density crossover in a deep magma ocean, Earth and Planetary Science Letters, 516, 202-211, https://doi.org/10.1016/j.epsl.2019.03.031, 2019.

196. Mashino, I., Miozzi, F., Hirose, K., Morard, G., Sinmyo, R., Melting experiments on the Fe–C binary system up to 255 GPa: Constraints on the carbon content in the Earth’s core, Earth and Planetary Science Letters, 515, 135-144, https://doi.org/10.1016/j.epsl.2019.03.020, 2019.

195. Kusakabe, M., Hirose, K., Sinmyo, R., Kuwayama, Y., Ohishi, Y., Helffrich, G., Melting curve and equation of state of β-Fe7N3: Nitrogen in the core?, Journal of Geophysical Research, Solid Earth, 124, https://doi.org/10.1029/2018JB015823, 2019.

194. Sinmyo, R., Hirose, K., Ohishi, Y., Melting of iron to 290 gigapascals determined in a resistance-heated diamond-anvil cell, Earth and Planetary Science Letters, 510, 45–52, 2019.

193. Tateno, S., Komabayashi, T., Hirose, K., Hirao, N., Ohishi, Y., Static compression of B2 KCl to 230 GPa and its P-V-T equation of state, American Mineralogist, DOI: https://doi.org/10.2138/am-2019-6779, 2019.

192. Hasegawa, A., Ohta, K., Yagi, T., Hirose, K., Okuda, Y., Kondo, T., Composition and pressure dependence of lattice thermal conductivity of (Mg,Fe)O solid solutions, Comptes Rendus Geoscience, 351, 229–235, https://doi.org/10.1016/j.crte.2018.10.005, 2019.

191. Ohta, K., Suehiro, S., Hirose, K., Ohishi, Y., Electrical resistivity of fcc phase iron hydrides at high pressures and temperatures, Comptes Rendus Geoscience, 351, 147–153, https://doi.org/10.1016/j.crte.2018.05.004, 2019.

190. Badro, J., Aubert, J., Hirose, K., Nomura, R., Blanchard, I., Borensztajn, S., Siebert, J., Magnesium partitioning between Earth’s mantle and core and its potential to drive an early exsolution geodynamo, Geophysical Research Letters, 45, https://doi.org/10.1029/2018GL080405, 2018.

189. Ohta, K., Nishihara, Y., Satoh, Y., Hirose, K., Yagi, T., Kawaguchi, S. I., Hirao, N., Ohishi, Y., An experimental examination of thermal conductivity anisotropy in hcp iron, Frontiers in Earth Science, 6, 176, doi:10.3389/feart.2018.00176, 2018.

188. Ozawa, K., Anzai, M., Hirose, K., Sinmyo, R., Tateno, S., Experimental determination of eutectic liquid compositions in the MgO–SiO2 system to the lowermost mantle pressures, Geophysical Research Letters, 45, https:// doi.org/10.1029/2018GL079313, 2018.

187. Tateno, S., Hirose, K., Sakata, S., Yonemitsu, K., Ozawa, H., Hirata, T., Hirao, N., Ohishi, Y. Melting phase relations and element partitioning in MORB to lowermost mantle conditions, Journal of Geophysical Research, Solid Earth, 123,(2018), doi:10.1029/2018JB015790.

186. Helffrich, G., Shahar, A., Hirose, K., Isotopic signature of core-derived SiO2, American Mineralogist, 103, 1161–1164,2018.

185. Tateno, S., Hirose, K., Sinmyo, R., Morard, G., Hirao, N., Ohishi, Y., Melting of Fe–Si–S alloys to core pressures: silicon in the core?, American Mineralogist, 103, 742–748, 2018, doi:10.2138/am-2018-6299.

184. Sakai, T., Yagi, T., Irifune, T., Kadobayashi, H., Hirao, N., Kunimoto, T., Ohfuji, H., Kawaguchi, S., Ohishi, Y., Tateno, S., Hirose, K., High pressure generation using double-stage diamond anvil technique: problems and equations of state of rhenium, High Pressure Research, 2018, doi:10.1080/08957959.2018.1448082.

183. Helffrich, G., Ballmer, M., Hirose, K., Core-exsolved SiO2 dispersal in the Earth’s mantle, Journal of Geophysical Research, Solid Earth, 123, 176–188 2018, doi:10.1002/2017JB014865.

182. Wakamatsu, T., Ohta, K., Yagi, T., Hirose, K., Ohishi, Y., Measurements of sound velocity in iron-nickel alloys by femtosecond laser pulses in a diamond anvil cell, Physics and Chemistry of Minerals (2018), doi:10.1007/s00269-018-0944-3.

181. 廣瀬敬、地球コアの鉄、ふぇらむ、22, 20-24 (2017).

180. Hirose, K., Sinmyo, R., Hernlund, J., Perovskite in Earth’s deep interior, Science, 358, 734-738 (2017).

179. Suehiro, S., Ohta, K., Hirose, K., Morard, G., Ohishi, Y., The influence of sulfur on the electrical resistivity of hcp iron: implications for the core conductivity of Mars and Earth, Geophysical Research Letters, 44, 8254–8259 (2017),
doi:10.1002/ 2017GL07402

178. Kidokoro, Y., Umemoto, K., Hirose, K., Ohishi, Y., Phase transition in SiC from zinc-blende to rock-salt structure and implications for carbon-rich extrasolar planets, American Mineralogist, 102, 2230-2234, 2017.

177. Ballmer, M.D., Lourenço, D.L., Hirose, K., Caracas, R., Nomura, R., Reconciling magma-ocean crystallization models with the present-day structure of the Earth’s mantle, Geochemistry, Geophysics, Geosystems, 18, 2785–2806,

176. Okuda, Y., Ohta, K., Yagi, T., Sinmyo, R., Wakamatsu, T., Hirose, K., Ohishi, Y., The effect of iron and aluminum incorporation on lattice thermal conductivity of bridgmanite at the Earth’s lower mantle, Earth and Planetary Science Letters, 474, 25-31, 2017.

175. Kawaguchi, S., Nakajima, Y., Hirose, K., Komabayashi, T., Ozawa, H., Tateno, S., Kuwayama, Y., Tsutsui, S., Baron, A. Q. R., Sound velocity of liquid Fe–Ni–S at high pressure, Journal of Geophysical Research, Solid Earth, 122, 3624–3634, doi:10.1002/2016JB013609, 2017.

174. Ohta, K., Yagi, T., Hirose, K., Ohishi, Y.,
Thermal conductivity of ferropericlase in the Earth’s lower mantle,
Earth and Planetary Science Letters, 465, 29-37, 2017.

173. Ohta, K., Yagi, T., Hirose, K., Ohishi, Y.,
Thermal conductivity of ferropericlase in the Earth’s lower mantle,
Earth and Planetary Science Letters, 465, 29-37, 2017.

172. Mori, Y., Ozawa, H., Hirose, K., Sinmyo, R., Tateno, S., Morard, G., Ohishi, Y.,
Melting experiments on Fe-Fe3S system to 254 GPa,
Earth and Planetary Science Letters, 464, 135-141, 2017.

171. Ballmer, M., Houser, C., Hernlund, J., Wentzcovitch, R., Hirose, K.,
Persistence of strong silica-enriched domains in the Earth’s lower mantle,
Nature Geoscience, 10, 236-240, doi:10.1038/ngeo2898, 2017.

170. Hirose, K., Morard, G., Sinmyo, R., Umemoto, K., Hernlund, J., Helffrich, G., Labrosse, S.,
Crystallization of silicon dioxide and compositional evolution of the Earth’s core,
Nature, 543, 99-102, doi:10.1038/nature21367, 2017.

169. Ozawa, H., Hirose, K., Yonemitsu, K., Ohishi, Y.,
High-pressure melting experiments on Fe-Si alloys and implications for silicon as a light element in the core,
Earth and Planetary Science Letters, 456, 47-54, 2016.

168. Gomi, H., Hirose, K., Akai, H., Fei, Y.,
Electrical resistivity of substitutionally disordered hcp Fe-Si and Fe-Ni alloys: chemically induced resistivity saturation in the Earth’s core,
Earth and Planetary Science Letters, 451, 51-61, 2016.

167. Tagawa, S., Ohta, K., Hirose, K., Kato, C., Ohishi, Y.,
Compression of Fe-Si-H alloys to core pressures,
Geophysical Research Letters, 43, doi:10.1002/2016GL068848, 2016.

166. Umemoto, K., Kawamura, K., Hirose, K., Wentzcovitch, R. M.,
Post-stishovite transition in hydrous aluminous SiO2,
Physics of the Earth and Planetary Interiors, 255, 18-26, 2016.

165. Ohta, K., Kuwayama, Y., Hirose, K., Shimizu, K., Ohishi, Y.,
Experimental determination of the electrical resistivity of iron at Earth’s core conditions,
Nature, 534, 95-98, doi:10.1038/nature17957, 2016.

164. Kato, C., Hirose, K., Nomura, R., Miyake, A., Ohishi, Y.,
Melting in the FeO-SiO2 system to deep lower mantle pressures: implications for subducted Banded Iron Formations,
Earth and Planetary Science Letters, 440, 56-61, 2016.

163. Hirose, K.,
Phase transition and melting in the deep lower mantle,
AGU monograph “Deep Earth: Physics and Chemistry of the Lower Mantle and Core”, p. 209-224, 2016.

162. Nakajima, Y., Imada, S., Hirose, K., Komabayashi, T., Ozawa, H., Tateno, S., Tsutsui, S., Kuwayama, Y., Baron, A. Q. R.,
Carbon depleted outer core revealed by sound velocity measurements of liquid Fe-C alloy,
Nature Communications, 6:8942 doi:10.1038/ncomms9942, 2015.

161. Umemoto, K., Hirose, K.,
Liquid iron-hydrogen alloys at outer core conditions by first-principles calculations,
Geophysical Research Letters, 42, 7513-7520, doi:10.1002/2015GL065899, 2015.

160. Umemoto, K., Sugimura, E., de Gironcoli, S., Nakajima, Y., Hirose, K., Ohishi, Y., Wentzcovitch, R. M.,
Nature of the volume isotope effect in ice,
Physical Review Letters, 115, 173005, 2015.

159. Komabayashi, T., Kato, J., Hirose, K., Tsutsui, S., Imada, S, Nakajima, Y., Baron, A. Q. R.,
Temperature dependence of the velocity-density relation for liquid metals under high pressure: implications for the Earth’s outer core,
American Mineralogist, 100, 2602-2609, 2015.

158. Minobe, S., Nakajima, Y., Hirose, K., Ohishi, Y.,
Stability and compressibility of a new iron-nitride β-Fe7N3 to core pressures,
Geophysical Research Letters, 42, doi:10.1002/2015GL064496, 2015.

157. Gomi, H., Hirose, K., Electrical resistivity and thermal conductivity of hcp Fe-Ni alloys under high pressure: Implications for thermal convection in the Earth’s core,
Physics of the Earth and Planetary Interiors, doi:10.1016/j.pepi.2015.04.003, 2015.

156. Labrosse, S., Hernlund, J., Hirose, K.,
Fractional melting and freezing in the deep mantle and implications for the formation of a basal magma ocean,
In: “Early Earth: Accretion and Differentiation”, AGU monograph, 212, 111-130, 2015.

155. Hirose, K., Wentzcovitch, R., Yuen, D., Lay, T.,
Mineralogy of the deep mantle - the post-perovskite phase and its geophysical significance,
In: Gerald Schubert (editor-in-chief) Treatise on Geophysics, 2nd edition, Vol 2.
Oxford: Elsevier; p. 85-115, 2015

154. Tateno, S., Kuwayama, Y., Hirose, K., Ohishi, Y.,
Crystal structure of Fe-Si alloy in the Earth’s inner core,
Earth and Planetary Science Letters, 418, 11-19, 2015.

153. Wentzcovitch, R., Umemoto, K., Kawamura, K., Hirose, K.,
Post-stishovite transition in hydrous aluminous SiO2,
Earth and Planetary Science Letters, 418, 11-19, 2015.

152. Tateno, S., Kuwayama, Y., Hirose, K., Ohishi, Y.
The structure of Fe-Si alloy in Earth’s inner core,
Earth and Planetary Science Letters, 418, 11-19, 2015.

151. Tatsumi, Y., Suzuki, T., Ozawa, H., Hirose, K., Hanyu, T., Ohishi, Y.,
Accumulation of ‘anti-continent’ at the base of the mantle and its recycling in mantle plumes,
Geochimica et Cosmochimica Acta, 143, 23-33, 2014.

150. Caracas, R., Ozawa, H., Hirose, K., Ishii, H., Hiraoka, N., Ohishi, Y., Hirao, N.,
Chemistry and Mineralogy of Earth’s Mantle,
American Mineralogist, 99(7), 1270-1276, 2014.

149. Ohta, K., Yagi, T., Hirose, K.,
Thermal diffusivities of MgSiO3 and Al-bearing MgSiO3 perovskites,
American Mineralogist, 99(1), 94-97, 2014.

148. Umemoto, K., Hirose, K., Imada, S., Nakajima, Y., Komabayashi, T., Tsutsui, S., Baron, A. Q.,
Liquid iron-sulfur alloys at outer core conditions by first principles calculations,
Geophysical Research Letters, 41(19), 6712-6717, 2014.

147. Imada, S., Ohta, K., Yagi, T., Hirose, K., Yoshida, H., Nagahara, H.,
Measurements of lattice thermal conductivity of MgO to core mantle boundary pressures,
Geophysical Research Letters, 41(13), 4542-4547, 2014.

146. Tateno, S., Hirose, K., Ohishi, Y.,
Melting experiments on peridotite to lowermost mantle conditions,
Journal of Geophysical Research: Solid Earth, 119(6), 4684-4694, 2014.

145. Nomura, R., Hirose, K., Uesugi, K., Ohishi, Y., Tsuchiyama, A., Miyake, A., Ueno, Y.
Low core-mantle boundary temperature inferred from the solidus of pyrolite,
Science, 343(6170), 522-525, 2014.

144. Kato, C., Hirose, K., Komabayashi, T., Ozawa, H., Ohishi, Y.,
NAL phase in K-rich portions of the lower mantle,
Geophysical Research Letters, 40(19), 5085-5088, 2013.

143. Ozawa, H., Hirose, K., Suzuki, T., Ohishi, Y., Hirao, N.,
Decomposition of Fe3S above 250 GPa,
Geophysical Research Letters, 40(18), 4845-4849, 2013.

142. Asahara, Y., Hirose, K., Ohishi, Y., Hirao, N., Ozawa, H., Murakami, M.,
Acoustic velocity measurement for stishovite across the post-stishovite phase transition under deviatoric stress: implication to the seismic feature of subducting slabs in the mid-mantle,
American Mineralogist, 98, 11-12, 2013.

141. Gomi, H., Ohta, K., Hirose, K., Labrosse, S., Caracas, R.,Verstraete, M.J., Hernlund, J.,
The high conductivity of iron and thermal evolution of the Earth’s core,
Physics of the Earth and Planetary Interiors, 224, 88-103, 2013.

140. Hirose, K., Labrosse, S., Hernlund, J.,
Composition and state of the core,
Annual Review of Earth and Planetary Sciences, in press.

139. Dai, L., Kudo, Y., Hirose, K., Murakami, M., Asahara, Y., Ozawa, H., Ohishi, Y., Hirao, N.,
Sound velocities of Na0.4Mg0.6Al1.6Si0.4O4 NAL and CF phases to 73 GPa determined by Brillouin scattering method,
Physics and Chemistry of Minerals, 40, 195-201, DOI 10.1007/s00269-012-0558-0, 2013.

138. Hirose, K.,
High-Pressure, High-Temperature X-ray Diffraction Measurements and the Discovery of Post-Perovskite Phase Transition,
Journal of the Physical Society of Japan, 82, 021010, doi: 10.7566/JPSJ.82.021010, 2013.

137. Noguchi, M., Komabayashi, T., Hirose, K., Ohishi, Y.,
High-temperature compression experiments of CaSiO3 perovskite to lowermost mantle conditions and its thermal equation of state,
Physics and Chemistry of Minerals, 40, 81-91, DOI 10.1007/s00269-012-0549-1, 2013.

136. Sinmyo, R., Hirose, K.,
Iron partitioning in pyrolitic lower mantle,
Physics and Chemistry of Minerals, 40, 107-113, DOI 10.1007/s00269-012-0551-7, 2013.

135. Sugimura, E., Komabayashi, T., Ohta, K., Hirose, K., Ohishi, Y.,
Dubrovinsky, L., Experimental evidence for superionic conduction in H2O ice,
Journal of Chemical Physics, 137, 194505, 2012.

134. Kato, J., Hirose, K., Ohishi, Y.,
High-pressure experiments on phase transition boundaries between corundum, Rh2O3(II) and CaIrO3-type structures in Al2O3,
American Mineralogist, in press.

133. Kudo, Y., Hirose, K., Murakami, M., Asahara, Y., Ozawa, H., Ohishi, Y., Hirao, N.,
Sound velocity measurements of CaSiO3 perovskite to 133 GPa and implications for lowermost mantle seismic anomalies,
Earth and Planetary Science Letters, 349/350, 1-7, 2012.

132. Ohta, K., Yagi, T., Taketoshi, N., Hirose, K., Komabayashi, T., Baba, T., Ohishi, Y., Hernlund, J.,
Lattice thermal conductivity of MgSiO3 perovskite and post-perovskite at the core-mantle boundary,
Earth and Planetary Science Letters, 349/350, 109-115, 2012.

131. Tateno, S., Hirose, K., Komabayashi, T., Ozawa, H., Ohishi, Y.,
The structure of Fe-Ni alloy in Earth’s inner core,
Geophysical Research Letters, 39, L12305, doi:10.1029/2012GL052103, 2012.

130. Imada, S., Hirose, K., Komabayashi, T., Suzuki, T., Ohishi, Y.,
Compression of Na0.4Mg0.6Al1.6Si0.4O4 the NAL and Ca-ferrite type phases,
Physics and Chemistry of Minerals, DOI 10.1007/s00269-012-0508-x, 2012.

129. Murakami, M., Ohishi, Y., Hirao, N., Hirose, K.,
A perovskititic lower mantle inferred from high pressure and temperature sound velocity data,
Nature, 485, 90-94, doi:10.1038nature11004, 2012.

128. Komabayashi, T., Hirose, K., Ohishi, Y.,
In-situ X-ray diffraction measurements of the fcc-hcp phase transition boundary of an Fe-Ni alloy in an internally-heated diamond anvil cell,
Physics and Chemistry of Minerals, 39, 329-338, doi: 10.1007/s00269-012-0490-3, 2012.

127. Ohta, K., Cohen, R. E., Hirose, K., Haule, K., Shimizu, K., Ohishi, Y.,
Experimental and theoretical evidence for pressure-induced metallization in FeO with rocksalt-type structure,
Physical Review Letters, 108, 026403, 2012.

126. Yamanaka, T., Hirose, K., Mao, W. L., Meng, Y., Ganesh, P., Shulenburger, L., Shen, G., Hemley, R. J.,
Crystal structures of (Mg1-x,Fex)SiO3 post-perovskite at high pressures,
Proceedings of the National Academy of Sciences of USA, 109, 1035-1040, doi:10.1073/pnas.1118076108, 2012.

125. Ozawa, H., Takahashi, F., Hirose, K., Ohishi, Y., Hirao, N.,
Phase transition in FeO and stratification in Earth’s outer core,
Science, 334, 792-794, 2011.

124. Ozawa, H., Hirose, K., Ishii, H., Hiraoka, N., Ohishi, Y., Seto, Y.,
Spin crossover, structural change, and metallization in FeO with NiAs-type structure,
Physical Review B, 84, 134417 (2011).

123. Kuwayama, Y., Hirose, K., Sata, N., Ohishi, Y.,
Pressure-induced structural evolution of pyrite-type SiO2,
Physics and Chemistry of Minerals, 38, 591-597 (2011), doi:10.1007/s00269-011-0431-6.

122. Imada, S., Hirose, K., Ohishi, Y.,
Stabilities of NAL and Ca-ferrite-type phases on the join NaAlSiO4-MgAl2O4 at high pressure,
Physics and Chemistry of Minerals, 38, 557-560 (2011), doi:10.1007/s00269-011-0427-2.

121. Nakajima, Y., Takahashi, E., Sata, N., Nishihara, Y., Hirose, K., Funakoshi, K., Ohishi, Y.,
Thermoelastic property and high-pressure stability of Fe7C3: Implication for iron-carbide in the Earth’s core,
American Mineralogist, 96, 1158-1165 (2011).

120. Sinmyo, R., Hirose, K., Muto, S., Ohishi, Y., Yasuhara, A.,
The valence state and partitioning of iron in Earth’s lowermost mantle,
Journal of Geophysical Research, 116, B07205 (2011), doi:10.1029/2010JB008179.

119. Nomura, R., Ozawa, H., Tateno, S., Hirose, K., Hernlund, J., Muto, S., Ishii, H., Hiraoka, N.,
Spin crossover and iron-rich silicate melt in the Earth’s deep mantle,
Nature, 473, 199-202 (2011), doi:10.1038/nature09940.

118. Ohta, K., Hirose, K., Shimizu, K., Ohishi, Y.,
Experimental evidence for metal FeO with normal NiAs-type structure,
Physical Review B, 82, 174120 (2010).

117. 佐多永吉、廣瀬敬、松井正典、平尾直久、
レーザーアニール法を用いた体積測定に基づいた室温圧力スケールの比較、
高圧力の科学と技術、20巻(3)、240-243 (2010).

116. Asahara, Y., Hirose, K., Ohishi, Y., Hirao, N.,
Thermoelastic properties of ice VII and its high-pressure polymorphs: Implications for dynamics of cold slab subduction in the lower mantle,
Earth and Planetary Science Letters, 299, 474-482 (2010).

115. Hirose, K., Nagaya, Y., Merkel, S., Ohishi, Y.,
Deformation of MnGeO3 post-perovskite at lower mantle pressure and temperature,
Geophysical Research Letters, 37, L20302, doi:10.1029/2010GL044977 (2010).

114. Sugimura, E., Komabayashi, T., Hirose, K., Sata, N., Ohishi, Y., Dubrovinsky, L. S.,
Simultaneous high-pressure and -temperature volume measurements of ice VII and its thermal equation of state,
Physical Review B, 82, 134103 (2010).

113. Yagi, T., Ohta, K., Kobayashi, K., Taketoshi, N., Hirose, K., Baba, T.,
Thermal diffusivity measurement in diamond anvil cell using light pulse thermoreflectance technique,
Measurement Science and Technology, 22, 024011 (2011).

112. Tateno, S., Hirose, K., Ohishi, Y., Tatsumi, Y.,
The structure of iron in Earth’s inner core,
Science, 330, 359-361 (2010).

111. Nomura, R., Hirose, K., Sata, N., Ohishi, Y.,
Precise determination of post-stishovite phase transition boundary and implications for seismic heterogeneities in the mid-lower mantle,
Physics of the Earth and Planetary Interiors, 183, 104-109 (2010).

110. Komabayashi, T., Hirose, K., Sugimura, E., Sata, N., Ohishi, Y.,
High-temperature compression of ferropericlase and the effect of temperature on iron spin transition,
Earth and Planetary Science Letters, 297, 691-699 (2010).

109. 廣瀬敬
マントル進化の謎を解くマントルD”層、日経サイエンス、9月号、72-80 (2010).

108. Hirose, K.,
The Earth’s missing ingredient,
Scientific American, June issue, 32-37, 2010.

107. Sata, N., Hirose, K., Shen, G., Ohishi, Y., Hirao, N.,
Compression of FeSi, Fe3C, Fe0.95O, and FeS under the core pressures and implication for light element in the Earth’s core,
Journal of Geophysical Research, 115, B09204, doi:10.1029/2009JB006975 (2010).

106. Tateno, S., Hirose, K., Sata, N., Ohishi, Y.,
Structural distortion of CaSnO3 perovskite under pressure and the quenchable post-perovskite phase as a low-pressure analogue to MgSiO3,
Physics of the Earth and Planetary Interiors, 181, 54-59 (2010).

105. Hirose, K.,
Deep mantle properties,
Science, 327, 151-152, 2010.

104. Ohta, K., Hirose, K., Shimizu, K.,
The electrical resistance measurements of (Mg,Fe)SiO3 perovskite and implications for iron spin transition,
Physics of the Earth and Planetary Interiors, 180, 154-158, 2010.

103. Ohta, K., Hirose, K., Shimizu, K., Sata, N., Ohishi, Y.,
Electrical conductivities of pyrolitic mantle and MORB materials up to the lowermost mantle conditions,
Earth and Planetary Science Letters, 289, 497-502, 2010.

102. Asahara, Y., Murakami, M., Ohishi, Y., Hirao, N., Hirose, K.,
Sound velocity measurement in liquid water up to 25 GPa and 900 K: Implications for densities of water at lower mantle conditions,
Earth and Planetary Science Letters, 289, 479-485, 2010.

101. Sinmyo, R., Hirose, K.,
The Soret effect in laser-heated diamond-anvil cell,
Physics of the Earth and Planetary Interiors, 180, 172-178, 2010.

100. Ozawa, H., Hirose, K., Tateno, S., Sata, N., Ohishi, Y.,
Phase transition boundary between B1 and B8 structures of FeO up to 210 GPa,
Physics of the Earth and Planetary Interiors, 179, 157-163, 2010.

99. Yamamoto, S., Komiya, T., Hirose, K., Maruyama, S.,
Coesite and clinopyroxene exsolution lamellae in chromites: In-situ ultrahigh-pressure evidence from podiform chromitites in the Luobusa ophiolite, southern Tibet,
Lithos, 109, 314-322, 2009.

98. Kuwayama, Y., Sawai, T., Hirose, K., Sata, N., Ohishi, Y.,
Phase relations of iron-silicon alloys at high pressure and high temperature,
Physics and Chemistry of Minerals, 36, 511-518, DOI 10.1007/s00269-009-0296-0, 2009.

97. 廣瀬敬
高圧実験とマントルの相転移、
地震、61巻特集号、S273-S283、2009。

96. Ozawa, H., Hirose, K., Mitome, M., Bando, Y., Sata, N., Ohishi, Y.,
Experimental study of reaction between perovskite and molten iron to 146 GPa and implications for chemical equilibrium at the core-mantle boundary,
Physics and Chemistry of Minerals, 36, 355-363, 2009.

95. Fukao, Y., Obayashi, M., Nakakuki, T., and the Deep Slab Project Group (Utada, H., Suetsugu, D., Irifune, T., Ohtani, E., Yoshioka, S., Shiobara, H., Kanazawa, T., and Hirose, K.), Stagnant slab: A review,
Annual Review of the Earth and Planetary Science, 37, 19-46, 2009.

94. Tateno, S., Sinmyo, R., Hirose, K., Nishioka, H.,
The advanced ion-milling method for preparation of thin film using Ion Slicer: Application to a sample recovered from diamond-anvil cell,
Review of Scientific Instruments, 80, 013901, 2009.

93. Tateno, S., Hirose, K., Sata, N., Ohishi, Y.,
Determination of post-perovskite phase transition boundary in MgSiO3 up to 4400 K and implications for thermal structure at the base of the mantle,
Earth and Planetary Science Letters, 277, 130-136, 2009.

92. Murakami, M., Ohishi, Y. Hirao, N., Hirose, K.,
Elasticity of MgO to 130 GPa: Implications for lower mantle mineralogy,
Earth and Planetary Science Letters, 277, 123-129, 2009.

91. Sinmyo, R., Hirose, K., Nishio-Hamane, D., Seto, Y., Fujino, K., Sata, N., Ohishi, Y.,
Partitioning of iron between perovskite/post-perovskite and ferropericlase in the lower mantle,
Journal of Geophysical Research, 113, B11204, doi:10.1029/2008JB005730, 2008.

90. Murakami, M., Asahara, Y., Ohishi, Y., Hirao, N., Hirose, K.,
Development of in-situ Brillouin spectroscopy at high pressure and temperature with synchrotron radiation and infrared laser heating system: Application to the Earth’s deep interior,
Physics of the Earth and Planetary Interiors, 174, 282-291, 2009.

89. 太田健二、廣瀬敬、新名良介、小野田朱々江、清水克哉、
レーザー加熱式ダイヤモンドセルを用いた(Mg,Fe)SiO3ポストペロフスカイト相の電気伝導度測定、
高圧力の科学と技術、18巻(3)、260-266、2008.

88. Kuwayama, Y., Hirose, K., Sata, N., Ohishi, Y.,
Phase relations of iron and iron-nickel alloys up to 300 GPa; Implications for the composition and the structure of the Earth’s inner core,
Earth and Planetary Science Letters, 273, 379-385, 2008.

87. Ohishi, Y., Hirao, N., Sata, N., Hirose, K., Takata, M.,
Highly intense monochromatic X-ray diffraction facility for high-pressure research at SPring-8,
High Pressure Research, 28, 163-173, 2008.

86. Sinmyo, R., Ozawa, H., Hirose, K., Yasuhara, A., Endo, N.,
Ferric iron content in (Mg,Fe)SiO3 perovskite and post-perovskite in the deep lower mantle conditions,
American Mineralogist, 93, 1899-1902, 2008.

85. Hirose, K., Takafuji, N., Fujino, K., Shieh, S. R., Duffy, T. S.,
Iron partitioning between perovskite and post-perovskite: A transmission electron microscope study,
American Mineralogist, 93, 1678-1681, 2008.

84. Sugimura, E., Iitaka, T., Hirose, K., Kawamura, K., Sata, N., Ohishi, Y.,
The compression of H2O ice to 126 GPa and implications for hydrogen-bond symmetrization: Synchrotron x-ray diffraction measurements and density-functional calculations,
Physical Review B, 77, 214103, 2008.

83. Wu, Z., R. Wentzcovitch, K. Umemoto, Li, B., Hirose, K., Zheng, J,
PVT relations in MgO: an ultra-high P-T scale for planetary science applications,
Journal Geophysical Research, 113, B06204, doi:10.1029/2007JB005275, 2008.

82. Hirose, K., Sata, N., Komabayashi, T., Ohishi, Y.,
Simultaneous volume measurements of Au and MgO to 140 GPa and thermal equation of state of Au based on MgO pressure scale,
Physics of the Earth and Planetary Interiors, 167, 149-154, 2008.

81. Hirose, K., Lay, T.,
Discovery of post-perovskite phase transition and new views on the core-mantle boundary region,
Elements, 4, 183-189, 2008.

80. Ohta, K., Onoda, S., Hirose, K., Sinmyo, R., Shimizu, K., Sata, N., Ohishi, Y., Yasuhara, A.,
The electrical conductivity of post-perovskite in Earth’s D” layer,
Science, 320, 89-91, 2008.

79. Ozawa, H., Hirose, K., Mitome, M., Bando, Y., Sata, N., Ohishi, Y.,
Chemical equilibrium between ferropericlase and molten iron to 134 GPa and implications for iron content at the bottom of the mantle,
Geophysical Research Letters, 35, L05308, doi:10.1029/2007GL032648, 2008.

78. Ishibashi, K., Hirose, K., Sata, N., Ohishi, Y.,
Dissociation of CAS phase in the uppermost lower mantle,
Physics and Chemistry of Minerals, 35, 197-200, 2008.

77. Ohta, K., Hirose, K., Lay, T., Sata, N., Ohishi, Y.,
Phase transitions in pyrolite and MORB at lowermost mantle conditions: Implications for a MORB-rich pile above the core-mantle boundary,
Earth and Planetary Science Letters, 267, 107-117, 2008.

76. Sata, N., Ohfuji, H., Hirose, K., Kobayashi, H., Ohishi, Y., Hirao, N.,
New high-pressure B2 phase of FeS above 180 GPa,
American Mineralogist, 93, 492-494, 2008.

75. Komabayashi, T., Hirose, K., Sugimura, E. Sata, N., Ohishi, Y, Dubrovinsky, L.,
Simultaneous volume measurements of perovskite and post-perovskite in MgSiO3 and their thermal equations of state,
Earth and Planetary Science Letters, 265, 515-524, 2008.

74. Hirose, K.,
Discovery of post-perovskite phase transition and the nature of D” layer, in Post-perovskite:
The Last Mantle Phase Transition, edited by K. Hirose, J. Brodholt, T. Lay and D. Yuen, AGU monograph, Ser. 174, 19-35, 2007.

73. Komabayashi, T., Hirose, K., Sata, N., Ohishi, Y, Dubrovinsky, L.,
Phase transition of CaSiO3 perovskite,
Earth and Planetary Science Letters, 260, 564-569, 2007.

72. Murakami, M., Sinogeikin, S., Bass, J., Sata, N., Ohishi, Y., Hirose, K.,
Sound velocity of MgSiO3 post-perovskite phase: A constraint on the D” discontinuity,
Earth and Planetary Science Letters, 259, 18-23, 2007.

71. Ohta, K., Hirose, K., Onoda, S., Shimizu, K.,
The effect of iron spin transition on electrical conductivity of (Mg,Fe)O magnesiow?stite,
Proceedings of the Japan Academy, Ser. B., 83, 97-100, 2007.

70. Ohfuji, H., Sata, N., Kobayashi, H., Ohishi, Y., Hirose, K., Irifune, T.,
A new high-pressure and high-temperature polymorph of FeS,
Physics and Chemistry of Minerals, 10.1007/s00269-007-0151-0, 2007.

69. Tateno, S., Hirose, K., Sata, N., Ohishi, Y.,
High solubility of FeO in perovskite and the post-perovskite phase transition,
Physics of the Earth and Planetary Interiors, 160, 319-325, 2007.

68. Hirose, K.,
Post-perovskite phase transition and the nature of D” layer, Superplumes:
Beyond Plate Tectonics, edited by D. A. Yuen, S. Maruyama, S. Karato, and B. F. Windley, Springer, pp. 69-82, 2007.

67. 廣瀬敬
ついに見えてきた地球コア直上の世界、
日経サイエンス、1月号、42-49、2007.

66. Hirose, K., Kawamura, K.,
Discovery of post-perovskite phase transition and implications for the nature of D” layer of the mantle,
Advances in High-Pressure Mineralogy, edited by E. Ohtani, GSA Memoir Special paper, 421, 37-46, 2007.

65. Hirose, K.,
Postperovskite phase transition and its geophysical implications,
Reviews of Geophysics, 44, RG3001, doi:101029/2005RG000186, 2006.

64. Sinmyo, R., Hirose, K., O’Neill, H.St.C., Okunishi, E.,
Ferric iron in Al-bearing post-perovskite,
Geophysical Research Letters, 33, L12S13, doi:10.1029/2006GL025858, 2006.

63. 廣瀬敬
超高圧実験で探る地球深部、
日本地球惑星科学連合ニュースレター(JGL)、8月号、3-5、2006.

62. 廣瀬敬
急速に理解の進むマントル最深部、
科学、5月号、455-456、6-7、2006.

61. 廣瀬敬
超高圧実験で探るマントル最深部、
日本地震学会広報紙ないふる、1月号、2006.

60. Hirose, K., Karato, S., Cormier, V., Brodholt, J., Yuen, D.,
Unsolved problems in the lowermost mantle,
Geophysical Research Letters, 33, L12S01, doi:10.1029/2006GL025691, 2006.

59. Shieh, S., Duffy, T., Kubo, A., Shen, G., Prakapenka, V., Sata, N., Hirose, K., Ohishi, Y.,
Equation of state of the post-perovskite phase synthesized from a natural (Mg,Fe)SiO3 orthopyroxene,
Proceedings of the National Academy of Sciences of USA, 103, 3039-3043, 2006.

58. Hirose, K., Sinmyo, R., Sata, N., Ohishi, Y.,
Determination of post-perovskite phase transition boundary in MgSiO3 using Au and MgO internal pressure standards,
Geophysical Research Letters, 33, L01310, doi:10.1029/2005GL024468, 2006.

57. Tateno, S., Hirose, K., Sata, N., Ohishi, Y.,
High-pressure behavior of MnGeO3 and CdGeO3 and the post-perovskite phase transition,
Physics and Chemistry of Minerals, 32, 721-725, 2006.

56. 廣瀬敬
マントル最深部の新鉱物の発見、
科学、8月号、1024-1028、2005.

55. 廣瀬敬
地球惑星内部物質の放射光結晶学、
日本結晶学会誌、47巻(4)、247-252、2005.

54. Kuwayama, Y., Hirose, K., Sata, N., Ohishi, Y.,
The pyrite-type high-pressure form of silica,
Science, 309, 923-925, 2005.

53. Tateno, S., Hirose, K., Sata, N., Ohishi, Y.,
Phase relations in Mg3Al2Si3O12 to 180 GPa: Effect of Al on post-perovskite phase transition,
Geophysical Research Letters, 32, L15306, doi:10.1029/2005GL023309, 2005.

52. Hirose, K., Takafuji, N., Sata, N., Ohishi, Y.,
Phase transition and density of subducted MORB crust in the lower mantle,
Earth and Planetary Science Letters, 237, 239-251, 2005.

51. Komabayashi, T., Hirose, K., Funakoshi, K.,
In-situ X-ray measurements on the phase relation of antigorite (serpentine): implications for water transportation by slab peridotite into the deep interior,
Physics of the Earth and Planetary Interiors, 151, 276-289, 2005.

50. Hirose, K., Y. Fujita,
Clapeyron slope of the post-perovskite phase transition boundary in CaIrO3,
Geophysical Research Letters, 32, L13313, doi:10.1029/2005GL023219, 2005.

49. Takafuji, N., Hirose, K., Mitome, M., Bando, Y.,
Solubilities of O and Si in liquid iron in equilibrium with (Mg,Fe)SiO3 perovskite and the light elements in the core,
Geophysical Research Letters, 32, L06313, doi:10.1029/2005GL022773, 2005.

48. Murakami, M., Hirose, K., Sata, N., Ohishi, Y.,
Post-perovskite phase transition and crystal chemistry in the pyrolitic lowermost mantle,
Geophysical Research Letters, 32, L03304, doi:10.1029/2004GL021956, 2005.

47. 廣瀬敬・河村雄行、
MgSiO3のポストペロブスカイト相の発見、
固体物理、40巻(2)、51-59、2005

46. 廣瀬敬
マントル最下層の新鉱物、
パリティ、20巻(1)、56-57、2005

45. Hirose, K., Kawamura, K., Tateno, S., Sata, N., Ohishi, Y.,
Stability and equation of state of MgGeO3 post-perovskite phase,
American Mienralogist, 90, 262-265, 2005.

44. 廣瀬敬
マントル最下層物質の結晶構造の発見、
パリティ、19巻(12)、58-61、2004

43. 廣瀬敬・河村雄行、
MgSiO3のポストペロブスカイト相転移の発見と地球の最下部マントル、
高圧力の科学と技術、14巻、265-274、2004

42. Takafuji, N., Hirose, K., Ono, S., Xu, F., Mitome, M., Bando, Y.,
Segregation of core melts by permeable flow in the lower mantle,
Earth and Planetary Science Letters, 224, 249-257, 2004.

41. Iitaka, T., Hirose, K., Kawamura, K., Murakami, M.,
The elasticity of MgSiO3 post-perovskite phase at the Earth’s lowermost mantle,
Nature, 430, 442-445, 2004.

40. Fei, Y., Li, J., Hirose, K., Minarik, W., Van Orman, J., Sanloup, C., van Westrenen, W., Komabayashi, T., Funakoshi, K.,
A critical evaluation of pressure scales at high temperatures by in-situ X-ray diffraction measurements,
Physics of the Earth and Planetary Interiors, 143-144, 515-526, 2004.

39. Murakami, M., Hirose, K., Ono, S., Isshiki, M., Watanuki, T.,
High pressure and high temperature phase transitions of FeO,
Physics of the Earth and Planetary Interiors, 146, 273-282, 2004.

38. Hirose, K., Shimizu, N., van Westrenen, W., Fei, Y.,
Trace element partitioning in Earth’s lower mantle and implications for the geochemical consequences of partial melting at the core-mantle boundary,
Physics of the Earth and Planetary Interiors, 146, 249-260, 2004.

37. Kurashina, T., Hirose, K., Ono, S., Sata, N., Ohishi, Y.,
Phase transition in Al-bearing CaSiO3-rich perovskite: implications for seismic discontinuities in the lower mantle,
Physics of the Earth and Planetary Interiors, 145, 67-74, 2004.

36. Miyazaki, A., Hiyagon, H., Sugiura, N., Hirose, K., Takahashi, E.,
Solubilities of nitrogen and noble gases in silicate melts under various oxygen fugacities: implications for the origin and degassing history of nitrogen and noble gases in the Earth,
Geochimica Cosmochimica et Acta, 68, 387-401, 2004.

35. Murakami, M., Hirose, K., Kawamura, K., Sata, N., Ohishi, Y.,
Post-perovskite phase transition in MgSiO3,
Science, 304, 855-858, 2004.

34. Fei, Y., Van Orman, J., Li, J., van Westrenen, W., Sanloup, C., Minarik, W., Hirose, K., Komabayashi, T., Walter, M., Funakoshi, K.,
In situ X-ray diffraction measurements of the post-spinel transition boundary in Mg2SiO4 by multiple internal pressure standards,
Journal of Geophysical Research, 109, doi:10.1029/2003JB002562, 2004.

33. Isshiki, M., Irifune, T., Hirose, K., Ono, S., Ohishi, Y., Watanuki, T., Nishibori, E., Sakata, M.,
Stability of magnesite and its new high-pressure form in the lower mantle,
Nature, 427, 60-62, 2004.

32. Katayama, I., Hirose, K., Yurimoto, H., Nakashima, S.,
Water solubility in majoritic garnet in MORB composition at the mantle transition zone,
Geophysical Research Letters, 30, doi:10.1029/2003GL018127, 2003.

31. Ono, S., Tsuchiya, T., Hirose, K., Ohishi, Y.,
Phase transition between the CaCl2-type and a-PbO2-type structures of germanium dioxide,
Physical Reviews B, 68, 134108, 2003.

30. Kuwayama, Y., Hirose, K.,
Phase relations in the system Fe-FeSi at 21 GPa,
American Mineralogist, 89, 273-276, 2004.

29. Ono, S., Tsuchiya, T., Hirose, K., Ohishi, Y.,
New high-pressure form of pyrite-type germanium dioxide,
Physical Reviews B, 68, 014103, 2003

28. Murakami, M., Hirose, K., Ono, S., Ohishi, Y.,
Stability of CaCl2-type and a-PbO2-type SiO2 determined by in situ X-ray observations,
Geophysical Research Letters, 30, 1207, 10.1029/2002GL016722, 2003.

27. Ono, S., Hirose, K., Isshiki, M., Mibe, K., Saito, Y.,
Equation of state of hexagonal aluminous phase of natural composition to 63 GPa at 300K,
Physics and Chemistry of Minerals, 29, 527-531, 2002.

26. Ono, S., Hirose, K., Kikegawa, T., Saito, Y.,
The compressibility of a natural composition calcium ferrite-type aluminous phase to 70 GPa,
Physics of the Earth and Planetary Interiors, 131, 311-318, 2002.

25. Ono, S., Suto, T., Hirose, K., Kuwayama, Y., Komabayashi, T. & Kikegawa, T.,
Equation of state of Al-bearing stishovite to 40 GPa at 300K,
American Mineralogist, 87, 1486-1489, 2002.

24. Hirose, K., Fei, Y.,
Subsolidus and melting phase relations of basaltic composition in the uppermost lower mantle,
Geochimica Cosmochimica et Acta, 66, 2099-2108, 2002.

23. Hirose, K.,
Phase transitions in pyrolitic mantle around 670-km depth: implications for upwelling of plumes from the lower mantle,
Journal of Geophysical Research, 107, 10.1029/2001JB000597, 2002.

22. Ono, S., Hirose, K., Murakami, M., Isshiki, M.,
Post-stishovite phase boundary in SiO2 determined by in situ X-ray determination,
Earth and Planetary Science Letters, 197, 187-192, 2002.

21. Murakami, M., Hirose, K., Yurimoto, H., Nakashima, S., Takafuji, N.,
Water in Earth’s lower mantle,
Science, 295, 1885-1887, 2002.

20. Ono, S., Hirose, K., Nishiyama N., Isshiki, M.,
Phase boundary between rutile-type and CaCl2-type germanium dioxide determined by in situ X-ray observations,
American Mineralogist, 87, 99-102, 2002.

19. Li, J., Fei, Y., Mao, H., Hirose, K., Shieh, S.,
Sulfur in the Earth’s inner core,
Earth and Planetary Science Letters, 193, 509-514, 2001.

18. Hirose, K., Komabayashi, T., Murakami, M., Funakoshi, K.,
In situ measurements of the majorite-akimotoite-perovskite phase transition boundaries in MgSiO3,
Geophysical Research Letters, 28, 4351-4354, 2001.

17. Shimizu, K., Komiya, T., Hirose, K., Shimizu, N., Maruyama, S.,
Cr-spinel, an excellent micro-container for retaining primitive melts – implications for a hydrous plume origin for komatiites,
Earth and Planetary Science Letters, 189, 177-188, 2001.

16. Miyajima, N., Yagi, T., Hirose, K., Kondo, T., Fujino, K., Miura, H.,
Potential host phase of aluminum and potassium in the Earth’s lower mantle,
American Mineralogist, 86, 740-746, 2001.

15. Hirose, K., Fei, Y., Ono, S., Yagi, T., Funakoshi, K.,
In situ measurements of the phase transition boundary in Mg3Al2Si3O12: implicationts for the nature of the seismic discontinuities in the Earth’s mantle,
Earth and Planetary Science Letters, 184, 567-573, 2001.

14. Hirose, K., Fei, Y., Ma, Y., Mao, H.,
The fate of subducted basaltic crust in the Earth’s lower mantle,
Nature, 397, 53-56, 1999.

13. Kogiso, T., Hirose, K.,., Takahashi, T.,
Melting experiments on homogeneous mixtures of peridotite and basalt: Application to the genesis of ocean island basalts,
Earth and Planetary Science Letters, 162, 45-61, 1998.

12. Hirose, K., Kushiro, I.,
The effect of melt segregation on polybaric mantle melting: estimation from the incremental melting experiments,
Physics of the Earth and Planetary Interiors, 107, 111-118, 1998.

11. Hirose, K.,
Partial melt compositions of carbonated peridotite at 3 GPa and genesis of alkali basalt magmas,
Geophysical Research Letters, 24, 2837-2840, 1997.

10. Peate, D., Pearce, J., Hawkesworth, C., Colley, H., Edwards, C., Hirose, K.,
Geochemical variations in Vanuatu arc lavas: the role of subducted material and a variable mantle wedge composition,
Journal of Petrology, 38, 1331-1358, 1997.

9. 廣瀬・久城、
マントルの融解とマグマの成因、
科学、3月号,194-202、1997.

8. Hirose, K.,
Melting experiments on lherzolite KLB-1 under hydrous conditions and generation of high-magnesian andesitic melts,
Geology, 25, 42-44, 1997.

7. Hirose, K., Kawamoto, T.,
Hydrous partial melting of lherzolite at 1GPa: the effect of H2O on the genesis of basaltic magmas,
Earth and Planetary Science Letters, 133, 463-473, 1995.

6. Kawamoto, T., Hirose, K.,
Au-Pd sample containers for melting experiments on iron and H2O bearing systems,
European Journal of Mineralogy, 6, 381-385, 1994.

5. Hirose, K., Kawamura, K.,
A new experimental approach for incremental batch melting of peridotite at 1.5 GPa,
Geophysical Research Letters, 21, 2139-214, 1994.

4. Nohara, M., Hirose, K., Eissen, J., Urabe, T., Joshima, M.,
The North Fiji Basin basalts and their magma sources; Part II Sr-Nd isotopic and trace element constraints,
Marine Geology, 116, 179-195, 1994.

3. Eissen, J., Nohara, M., Cotton, T., Hirose, K.,
North Fiji Basin basalts and their magma sources; Part I incompatible element constraints,
Marine Geology, 116, 153-178, 1994.

2. Hirose, K., Kushiro, I.,
Partial melting of dry peridotites at high pressures; determination of compositions of melts segregated from peridotite using aggregates of diamond,
Earth and Planetary Science Letters, 114, 477-489, 1993.

1. Kushiro, I., Hirose, K.,
Experimental determination of composition of melt formed by equilibrium partial melting of peridotite at high pressures using aggregates of diamond grains,
Proceedings of the Japan Academy, 68, 63-68, 1992.